I'd save all the raw gems for now. The only reason is that some time a socket bonus is worth it and some time it isn't. Take into account the meta gem requirements and it might be worth taking a lesser gem.
The best information I can provide is the stats needed for each class that can be upgraded with gems
Holy:
+heal
+spell crit
+mp5
+int
Prot:
+def (enduring talasite)
+dodge (subtle living ruby)
+stam (solid star of elune)
Ret:
+str
+attack
+crit
Rets LOVE my Inscribed Noble Topaz on the AH (+4 crit/+4 str)
As a jewelcrafter, I also have access to BoP Unique-Equipped gems and I have one of them where possible in all my sets:
Kailee's Rose +26 healing
Facet of Eternity +12 def
Stone of Blades +12 crit
Falling Star +18 stam
Pretty much all of my raid gear has Solid Stars, a Falling Star and Subtle Living Rubies. Too bad there isn't a +block rating gem yet.
My healing gear is a Kailee's Rose and a shitload of the teardrop blood garnets (+13 healing).
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Some people call me crazy but I like to think of myself as a freelance lunatic.
Ann Coulter is a Cylon